Silylene-bridged Dicopper Complex [Cu2(B(3,5-dime)BAPS)(μ-Si(CH3)2)2 (H2O) 2], [BAPS=bis(3-(2-hydroxybenzylideneamino) phenyl)sulfone]: Synthesis and Characterization
Philippine Journals Online
View Archive Info| Field | Value | |
| Title |
Silylene-bridged Dicopper Complex [Cu2(B(3,5-dime)BAPS)(μ-Si(CH3)2)2 (H2O) 2], [BAPS=bis(3-(2-hydroxybenzylideneamino) phenyl)sulfone]: Synthesis and Characterization
|
|
| Creator |
Lourdes P Guidote; Chemistry Department, De La Salle University-Manila
Victor Francis C Bathan; Chemistry Department, De La Salle University-Manila Francisco C Franco Jr; Chemistry Department, De La Salle University-Manila |
|
| Subject |
Chemistry
silylene complex, dicopper complex, Schlenk methods |
|
| Description |
Silylene-bridged dinuclear complexes have shown many interesting reactivities. Cu2(B(3,5- diMe)BAPS)(μ-OMe) 2 reacted with (CH3)3SiCl to yield a [μ-Si(CH3)2] dicopper complex. The reaction, separation, and drying of the product was carried out under dry nitrogen conditions. The reaction was monitored using thin layer chromatography (TLC) and the separations were done using column chromatography. The product was characterized using IR, NMR, UV-Vis and ES-MS. Analysis of the separated product supports the yielding of Cu2 (B(3.5-dime)BAPS)(μ- Si(CH3)2)2 (H2O) 2. Keywords: silylene complex, dicopper complex, Schlenk methodsDOI: 10.3860/jrsce.v4i2.449 JRSCE Vol.4(2) 2007 pp.23-29
|
|
| Publisher |
De La Salle University-Manila
|
|
| Contributor |
—
|
|
| Date |
2008-07-21
|
|
| Type |
Non-refereed item
|
|
| Format |
application/pdf
|
|
| Identifier |
http://www.philjol.info/index.php/JRSCE/article/view/449
|
|
| Source |
Journal of Research in Science, Computing and Engineering; Vol 4, No 2 (2007); 23-30
|
|
| Language |
en
|
|
| Coverage |
Philippines
— — |
|